Beilstein J. Org. Chem.2024,20, 734–740, doi:10.3762/bjoc.20.67
glutamate decarboxylase, and incubated with BaeJ-KS2. Substrate binding was demonstrated through 13C NMR analysis of the products against the background of various control experiments.
Keywords: bacillaene; biosynthesis; enzyme mechanisms; isotopes; trans-ATpolyketidesynthases; Introduction
Polyketides
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Graphical Abstract
Scheme 1:
Biosynthetic model for bacillaene (1). M1–M17 indicate modules 1–17. A = adenylation domain, ACP = ...